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Oral presentation

Dynamics of electrons in water produced by electron impact in the order of femtosecond

Kai, Takeshi; Yokoya, Akinari; Ukai, Masatoshi*; Fujii, Kentaro; Higuchi, Mariko; Watanabe, Ritsuko

no journal, , 

no abstracts in English

Oral presentation

Spur reactions of radiolysis of high concentrated sodium chloride solution

Hata, Kuniki; Yamashita, Shinichi*; Muroya, Yusa*; Katsumura, Yosuke*; Hanawa, Satoshi; Kasahara, Shigeki; Tsukada, Takashi

no journal, , 

To estimate primary yields of chemical species produced from radiolysis of aqueous solutions of high concentrated sodium chloride, a calculation using the diffusion kinetic model was employed. As a result of the sensitivity analysis on rate constants of reactions, it was shown that three reactions involving Cl$$^{-}$$ ion and OH radical play important roles in the primary yields.

Oral presentation

Synthesis of grafted cesium adsorbent in pilot scale

Hoshina, Hiroyuki; Kasai, Noboru; Ueki, Yuji; Saiki, Seiichi; Shibata, Takuya; Iwanade, Akio; Seko, Noriaki

no journal, , 

no abstracts in English

Oral presentation

Development of polymer gel dosimeter based on hydroxypropyl cellulose hydrogel; Toward the application on heavy ion therapy

Hiroki, Akihiro; Yamashita, Shinichi*; Taguchi, Mitsumasa; Murakami, Takeshi*

no journal, , 

no abstracts in English

Oral presentation

Decomposition of deoxyribose induced by soft X-ray exposure

Fujii, Kentaro; Izumi, Yudai; Narita, Ayumi; Yokoya, Akinari

no journal, , 

no abstracts in English

Oral presentation

Electric field effects on positron annihilation lifetime in kapton

Sakai, Hiroaki; Minei, Shuntaro; Hirade, Tetsuya; Oshima, Nagayasu*; Kobayashi, Yoshinori*; Kinomura, Atsushi*; Suzuki, Ryoichi*

no journal, , 

It was reported that positronium (Ps) formation probability was enhanced very much with very high electric fields. The spur reaction model can not explain this Ps formation. We tried to investigate this Ps formation with high electric fields in polyimide (kapton) that has no Ps formation with no electric field. Then we found out that Ps formation was not possible even at high electric fields. However, the annihilation lifetime of free positrons was elongated and it was probably caused by the positron drift movement.

Oral presentation

Nitrogen K-edge soft X-ray natural circular dichroism of histidine thin film

Izumi, Yudai; Tanaka, Masahito*; Tanigawa, Yoshiaki*; Momoki, Yohei*; Iwai, Miki*; Takenaka, Shun*; Ishiyama, Kimihiro*; Kuroki, Misa*; Muro, Takayuki*; Nakagawa, Kazumichi*

no journal, , 

It is unclear whether natural circular dichroism (NCD) originating from core-absorption of atoms located at various sites, as well as next to the asymmetric carbon, in the molecules can be observed selectively. In this study, we measured NCD spectra of an amino acid, histidine (His) which has three nitrogen atoms, thin film in the nitrogen K-edge energy region and confirmed whether we can pick up the NCD signals originating from each nitrogen atom throughout the molecules. NCD peaks assigned to the 1s $$rightarrow$$ $$pi$$$$^{*}$$ of the nitrogen atoms in imidazole ring and the 1s $$rightarrow$$ $$sigma$$$$^{*}$$ transition of the nitrogen atoms in imidazole ring and amino group. Imidazole ring and amino group are positioned at the side chain distant from and next to the asymmetric carbon, respectively. This result suggests that NCD spectroscopy in the soft X-ray region can selectively pick up the information on local structure around specific atoms, regardless of the position of atoms in molecules.

Oral presentation

The Behavior of radical decay in irradiated polyethylene nonwoven fabric

Saiki, Seiichi; Okaya, Keiko*; Seko, Noriaki; Kudo, Hisaaki*; Katsumura, Yosuke*

no journal, , 

no abstracts in English

Oral presentation

The Approach for volume reduction of contaminated plant wastes

Saiki, Seiichi; Hoshina, Hiroyuki; Shibata, Takuya; Ueki, Yuji; Kasai, Noboru; Seko, Noriaki

no journal, , 

no abstracts in English

Oral presentation

Micro/nanofabrication of poly(L-lactic acid) using quantum beams

Oyama, Tomoko; Hinata, Toru*; Nagasawa, Naotsugu; Oshima, Akihiro*; Washio, Masakazu*; Tagawa, Seiichi*; Taguchi, Mitsumasa

no journal, , 

Micro/nanofabrication of biocompatible and biodegradable poly(L-lactic acid) (PLLA) using quantum beams was evaluated for future bio-device applications. Electron beam nanoimprint lithography was proposed for fabricating micro/nanostructures of radiation-crosslinked-PLLA which has high thermal stability. Also, focused ion beam direct etching enabled controlled micro/nanofabrication of PLLA with C=C bond-rich surfaces which is expected to have good cell attachment properties.

Oral presentation

Crosslinking of natural polysaccarides in ionic liquids by ionizing radiation

Kimura, Atsushi; Nagasawa, Naotsugu; Taguchi, Mitsumasa

no journal, , 

Cellulose and chitin are plant- and shellfish-derived polysaccharides, respectively, and were irradiated with $$gamma$$ rays in room temperature ionic liquids to produce their chemical gels. The formation yields of the obtained cellulose and chitin gels depended on their initial concentrations, dissolved water content, dissolved oxygen concentration, and irradiation temperature, and reached up to 14 and 86%, respectively.

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